Delmas, Guo-Hua
and Benjelloun-Mlayah, Bouchra and Le Bigot, Yves and Delmas, Michel
Biolignin™ based epoxy resins.
(2013)
Journal of Applied Polymer Science, 127 (3). 1863-1872. ISSN 0021-8995
|
(Document in English)
PDF (Author's version) - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader 7MB |
Official URL: http://dx.doi.org/10.1002/app.37921
Abstract
Wheat straw Biolignin™ was used as a substitute of bisphenol-A in epoxy resin. Synthesis was carried out in alkaline aqueous media using polyethyleneglycol diglycidyl ether (PEGDGE) as epoxide agent. Structural study of Biolignin™ and PEGDGE was performed by solid-state 13C NMR and gel permeation chromatography, respectively, before epoxy resin synthesis. Biolignin™ based epoxy resins were obtained with different ratios of Biolignin™ : PEGDGE and their structures were analyzed by solid-state 13C NMR. The crosslinking of PEGDGE with Biolignin™ was highlighted in this study. Properties of Biolignin™ based epoxy resins were analyzed by differential scanning calorimetry and dynamic load thermomechanical analysis as well as compared with those of a bisphenol-A epoxy-amine resin. Depending on the epoxy resin formulation, results confirmed the high potential of Biolignin™ as a biosourced polyphenol used in epoxy resin applications.
| Item Type: | Article |
|---|---|
| HAL Id: | hal-03467413 |
| Audience (journal): | International peer-reviewed journal |
| Uncontrolled Keywords: | |
| Institution: | French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE) Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE) Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE) Other partners > Compagnie Industrielle de la Matière Végétale - CIMV (FRANCE) |
| Laboratory name: | |
| Statistics: | download |
| Deposited On: | 29 Oct 2013 07:42 |
Repository Staff Only: item control page
