Cardozo Perez, Andrés Fernando
and Manoury, Eric and Julcour-Lebigue, Carine and Blanco, Jean-François and Delmas, Henri and Gayet, Florence and Poli, Rinaldo
Preparation of phosphine-functionalized polystyrene stars by metal catalyzed controlled radical copolymerization and their application to hydroformylation catalysis.
(2013)
Dalton Transactions, 42 (25). 9148 -9156. ISSN 1477-9226
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(Document in English)
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Official URL: http://dx.doi.org/10.1039/c3dt33082f
Abstract
Well defined star copolymers have been prepared by copper-catalyzed atom transfer radical copolymerization of styrene and styryldiphenylphosphine starting from a modified Boltorn™ H30 multifunctional initiator. These polymers and an analogue obtained by debromination of the arm ends with nBu3SnH have been used in combination with [Rh(acac)(CO)2] for the homogeneous phase hydroformylation of 1-octene.
| Item Type: | Article |
|---|---|
| Additional Information: | Thanks to the Royal Society of Chemistry. The definitive version is available at http://pubs.rsc.org/en/content/articlepdf/2013/dt/c3dt33082f |
| Audience (journal): | International peer-reviewed journal |
| Uncontrolled Keywords: | |
| Institution: | French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE) Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE) Other partners > Institut universitaire de France - IUF (FRANCE) Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE) |
| Laboratory name: | |
| Statistics: | download |
| Deposited On: | 21 Oct 2013 14:39 |
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