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Recent progress in the shaping and sintering of barium titanate nanoparticles. Application to high permittivity capacitors.

Guillemet, Sophie and Voisin, Christophe and Nava Quintero, Román Jabir and Dufour, Pascal and Tenailleau, Christophe and Aguilar Garib, Juan Antonio and Reyes-Melo, Martin Edgar and Durand, Bernard Recent progress in the shaping and sintering of barium titanate nanoparticles. Application to high permittivity capacitors. (2012) In: Additional Conferences (Device Packaging, HiTEC, HiTEN, & CICMT). International Microelectronics Assembly and Packaging Society, 1-6.

(Document in English)

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Official URL: https://doi.org/10.4071/CICMT-2012-TP53


The miniaturisation of electronic components required for many devices involves an increase their volumic efficiency. This work focus on the size reduction of capacitors. They are two ways for increasing the capacity of such passive components. One is to find materials with high permittivity, the other is to reduce the thickness of the films used in multilayers ceramics. Barium titanate, BaTiO3 (BT) nanoparticles were sintered using Spark Plasma Sintering (SPS) because the material presents interesting properties when obtained by SPS [1-3]. In this case, very unusual interesting dielectric properties, a so called “colossal” permittivity value up to several thousands. Moreover, no temperature dependence is observed. However, the values of dielectric losses are too high to consider industrial applications. In order to reduce these dielectric losses, different approaches have been proposed to control the chemistry of grain boundaries. We present here the structural, microstructural and electrical properties of ceramics sintered by SPS from BaTiO3 powders elaborated by co-precipitation method. Different routes tested to improve the dielectric properties of the ceramics are presented and discussed.On the other side, thick films of BT have been prepared. The objective of this work was to develop a BaTiO3 material having an accurate particle size to reduce the thickness of sintered films down to 1 μm. The rheological properties of the slurry have been optimized and, thanks to a suitable tape casting process, homogeneous thin films of 1 μm thickness could be obtained. Some properties of the films are described.

Item Type:Book Section
HAL Id:hal-02045395
Audience (journal):International peer-reviewed journal
Audience (conference):International conference proceedings
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Other partners > Universidad Autónoma de Nuevo León - UANL (MEXICO)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Laboratory name:
Deposited On:22 Feb 2019 08:07

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