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Electrical properties of Mn₃-ₓCoₓO₄(0 ≤ x ≤ 3) ceramics: an interesting system for negative temperature coefficient thermistors

Rousset, Abel and Tenailleau, Christophe and Dufour, Pascal and Bordeneuve, Hélène and Pasquet, Isabelle and Guillemet, Sophie and Poulain, Véronique and Schuurman, Sophie Electrical properties of Mn₃-ₓCoₓO₄(0 ≤ x ≤ 3) ceramics: an interesting system for negative temperature coefficient thermistors. (2013) International Journal of Applied Ceramic Technology, 10 (1). 175-185. ISSN 1546-542X

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Official URL: http://dx.doi.org/10.1111/j.1744-7402.2011.02723.x

Abstract

Single-phase spinel manganese cobalt oxides Mn₃-ₓCoₓO₄ dense ceramics were prepared for the first time and their structural/electrical property relationships characterized. The electrical properties, that is, the resistivity at 25°C, the energetic constant, and the resistance drift at 125°C, were determined and correlated with the cation distribution. Finally, the electrical characteristics of the Mn₃-ₓCoₓO₄ system were compare'd with other important classes of manganese-based spinel oxides, Mn₃-ₓNiₓO₄ and Mn₃-ₓCuₓO₄, already commercialized as negative temperature coefficient (NTC) thermistors. The high values of energetic constant and low resistivities observed in Mn₃-ₓCoₓO₄ ceramics present a promising interest for such industrial applications.

Item Type:Article
HAL Id:hal-03526564
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Other partners > Vishay (BELGIUM)
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Deposited On:23 Sep 2013 14:06

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