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Dielectric properties of CaCu3Ti4O12 based multiphased ceramics

Guillemet, Sophie and Lebey, Thierry and Boulos, Madona and Durand, Bernard Dielectric properties of CaCu3Ti4O12 based multiphased ceramics. (2006) Journal of the European Ceramic Society, 2 (7). 1245-1257. ISSN 0955-2219

(Document in English)

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Official URL: http://dx.doi.org/10.1016/j.jeurceramsoc.2005.01.055


A “soft chemistry” method, the coprecipitation, has been used to synthesize the perovskite CaCu3Ti4O12 (CCT). Three main types of materials were obtained for both powders and sintered ceramics: a monophased consisting of the pure CCT phase, a biphased (CCT + CaTiO3), and a three-phased (CCT + CaTiO3 + copper oxide (CuO or Cu2O)). These ceramics, sintered at low temperature, 1050 °C, present original dielectric properties. The relative permittivity determined in the temperature range (−150 < T < 250 °C) is significantly higher than the one reported in the literature. Internal barrier layer capacitor is the probable mechanism to explain the particular behaviour. Moreover, the presence of a copper oxide phase beside the perovksite CCT plays an important role for enhancing the dielectric properties.

Item Type:Article
Additional Information:Thanks to Elsevier editor. The definitive version is available at http://www.sciencedirect.com The original PDF of the article can be found at Journal of the European Ceramic Society website : http://www.sciencedirect.com/science/journal/09552219
HAL Id:hal-03599312
Audience (journal):International peer-reviewed journal
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Institution:Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
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Deposited On:08 Sep 2008 14:29

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