Sharma, Amit and Julcour-Lebigue, Carine
and Deshpande, Raj M. and Kelkar, Ashutosh A. and Delmas, Henri
Hydroformylation of 1-Octene Using [Bmim][PF6]−Decane Biphasic Media and Rhodium Complex Catalyst: Thermodynamic Properties and Kinetic Study.
(2010)
Industrial & Engineering Chemistry Research, 49 (21). 10698-10706. ISSN 0888-5885
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(Document in English)
PDF (Author's version) - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader 941kB |
Official URL: http://dx.doi.org/10.1021/IE100222K
Abstract
A chemical reaction engineering approach is reported to investigate the biphasic hydroformylation of 1-octene using [bmim][PF6] ionic liquid. It is based both on a process parameter investigation (temperature, concentrations, and pressures) and a thermodynamic study of the reaction medium (gas−liquid and liquid−liquid equilibria). Initial rate data show complex behavior with respect to operating parameters and are best described by a rate equation based on a mechanistic model. Complete reaction scheme including isomerization is then modeled accounting from the time dependent concentration of the organic substrates measured in organic phase and recalculated in ionic liquid phase from liquid−liquid equilibria.
Item Type: | Article |
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HAL Id: | hal-02353556 |
Audience (journal): | International peer-reviewed journal |
Uncontrolled Keywords: | |
Institution: | French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE) Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE) Other partners > National Chemical Laboratory - NCL (INDIA) Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE) |
Laboratory name: | Laboratoire de Génie Chimique - LGC (Toulouse, France) - Réaction, mélange & séparation (RMS) |
Statistics: | download |
Deposited On: | 07 Jun 2012 09:59 |
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