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Catalytic hollow fiber membranes prepared using layer-by-layer adsorption of polyelectrolytes and metal nanoparticles

Ouyang, Lu and Dotzauer, David M. and Hogg, Seth R. and Macanás, Jorge and Lahitte, Jean-Francois and Bruening, Merlin L. Catalytic hollow fiber membranes prepared using layer-by-layer adsorption of polyelectrolytes and metal nanoparticles. (2010) Catalysis Today, 156 (3-4). 100-106. ISSN 0920-5861

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Official URL: http://dx.doi.org/10.1016/J.CATTOD.2010.02.040


Immobilization of metalnanoparticles in hollowfibermembranes via alternating adsorption of polyelectrolytes and negatively charged Au nanoparticles yields catalytic reactors with high surface areas. SEM images show that this technique deposits a high density of unaggregated metalnanoparticles both on the surfaces and in the pores of the hollowfibers. Catalytic reduction of 4-nitrophenol with NaBH4, which can be easily monitored by UV–vis spectrophotometry, demonstrates that the nanoparticles in the hollowfibermembrane are highly catalytically active. In a single pass through the membrane, >99% of the 4-nitrophenol is reduced to 4-aminophenol, but this conversion decreases over time. The conversion decline may stem from catalyst fouling caused by by-products of 4-aminophenol oxidation.

Item Type:Article
Additional Information:Thanks to Elsevier editor. The definitive version is available at http://www.sciencedirect.com The original PDF of the article can be found at : http://www.sciencedirect.com/science/article/pii/S0920586110001252
HAL Id:hal-03548747
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Other partners > Michigan State University - MSU (USA)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Laboratory name:
Laboratoire de Génie Chimique - LGC (Toulouse, France) - Génie des Interfaces & Milieux Divisés (GIMD)
Deposited On:31 May 2012 12:58

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