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Influence of pulse current during Spark Plasma Sintering evidenced on reactive alumina–hematite powders

Gurt Santanach, Julien and Estournès, Claude and Weibel, Alicia and Chevallier, Geoffroy and Bley, Vincent and Laurent, Christophe and Peigney, Alain Influence of pulse current during Spark Plasma Sintering evidenced on reactive alumina–hematite powders. (2011) Journal of the European Ceramic Society, 31 (13). 2247-2254. ISSN 0955-2219

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Official URL: http://dx.doi.org/10.1016/j.jeurceramsoc.2011.06.003


Spark Plasma Sintering (SPS) is increasingly used. The temperature and current are not independent parameters, making it difficult to separate the current intrinsic role from Joule heating. There is a debate on whether there are any specific SPS mechanisms. The influence of a key parameter, the (on:off) pulse pattern, is studied on the SPS of reactive α-Al2−2xFe2xO3 (x = 0.02; 0.05; 0.07; 0.10) powders. Changing it modifies the current crest intensity and has a great influence on the materials microstructure. Comparisons with runs where the current is blocked and hot-pressing reveal three competing phenomena: formation of FeAl2O4, dominant in the core and not peculiar to SPS, formation of Fe, producing Fe-Al2O3 composite surface layers, and most notably electrical-field induced diffusion of Fe3+ ions towards the cathode, which could have far-ranging implications for the consolidation of ionic materials and the in situ reactive shaping of composites and multimaterials.

Item Type:Article
Additional Information:Thanks to Elsevier editor. The definitive version is available at http://www.sciencedirect.com The original PDF of the article can be found at Journal of the European Ceramic Society website: http://www.sciencedirect.com/science/article/pii/S0955221911002974
HAL Id:hal-03542098
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
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Deposited On:15 May 2012 17:11

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