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Electrical conductivity and Raman imaging of double wall carbon nanotubes in a polymer matrix

Tishkova, Victoria and Raynal, Pierre Ivan and Puech, Pascal and Lonjon, Antoine and Le Fournier, Marion and Demont, Philippe and Flahaut, Emmanuel and Bacsa, Wolfgang Electrical conductivity and Raman imaging of double wall carbon nanotubes in a polymer matrix. (2011) Composites Science and Technology, 71 (10). 1326-1330. ISSN 0266-3538

(Document in English)

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Official URL: http://dx.doi.org/10.1016/j.compscitech.2011.05.001


Raman spectroscopy is used to access the dispersion state of DWNTs in a PEEK polymer matrix. The interaction of the outer tube with the matrix can be determined from the line shape of the Raman G band. This allows us to distinguish regions where the nanotubes are well dispersed and regions where the nanotubes are agglomerated. The percolation threshold of the electrical conductivity of the double wall carbon nanotubes (DWNTs)/PEEK nanocomposites is found to be at 0.2–0.3 wt.%. We find a maximum electrical conductivity of 3 x 10-2 S/cm at 2 wt.% loading. We detect nanotube weight concentrations as low as 0.16 wt.% by Raman spectroscopy using a yellow excitation wavelength. We compare the Raman images with transmission electron microscopy images and electrical conductivity measurements. A statistical method is used to find a quantitative measure of the DWNTs dispersion in the polymer matrix from the Raman images.

Item Type:Article
Additional Information:Thanks to Elsevier editor. The definitive version is available at http://www.sciencedirect.com The original PDF of the article can be found at Composites Science and Technology website: http://www.sciencedirect.com/science/article/pii/S0266353811001631
HAL Id:hal-00727199
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Laboratory name:
Deposited On:15 May 2012 16:55

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