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Transitions/relaxations in polyester adhesive/PET system

Carsalade, Elodie and Bernès, Alain and Lacabanne, Colette and Perraud, Sophie and Lafourcade, Michel and Savignac, Michel Transitions/relaxations in polyester adhesive/PET system. (2010) Journal of Thermal Analysis and Calorimetry, 101 (3). 849-857. ISSN 1388-6150

(Document in English)

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Official URL: http://dx.doi.org/10.1007/s10973-010-0834-5


The correlations between the transitions and the dielectric relaxation processes of the oriented poly(ethylene terephthalate) (PET) pre-impregnated of the polyester thermoplastic adhesive have been investigated by differential scanning calorimetry (DSC) and dynamic dielectric spectroscopy (DDS). The thermoplastic polyester adhesive and the oriented PET films have been studied as reference samples. This study evidences that the adhesive chain segments is responsible for the physical structure evolution in the PET-oriented film. The transitions and dielectric relaxation modes’ evolutions in the glass transition region appear characteristic of the interphase between adhesive and PET film, which is discussed in terms of molecular mobility. The storage at room temperature of the adhesive tape involves the heterogeneity of the physical structure, characterized by glass transition dissociation. Thus, the correlation between the transitions and the dielectric relaxation processes evidences a segregation of the amorphous phases. Therefore, the physical structure and the properties of the material have been linked to the chemical characteristics.

Item Type:Article
Additional Information:Thanks Springer editor. The definitive version is available at http://www.springerlink.com/ The original PDF of the article can be found at Journal of Thermal Analysis and Calorimetry website : http://www.springerlink.com/content/1388-6150/
HAL Id:hal-03549683
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National d'Études Spatiales - CNES (FRANCE)
French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Other partners > Zodiac Aerospace (FRANCE)
Laboratory name:
Deposited On:20 Jun 2011 15:04

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