OATAO - Open Archive Toulouse Archive Ouverte Open Access Week

A new route to prepare anodic coatings on dense and porous metallic supports for SOFC application

Rieu, Mathilde and Lenormand, Pascal and Panteix, Pierre Jean and Ansart, Florence A new route to prepare anodic coatings on dense and porous metallic supports for SOFC application. (2008) In: 35th International Conference on Metallurgical Coatings and Thin Films, 28 April 2008 - 2 May 2008 (San Diego, United States).

(Document in English)

PDF (Author's version) - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader

Official URL: http://dx.doi.org/10.1016/j.surfcoat.2008.08.015


Metallic cell supports have been developed for the new generation of fuel cells. Sol–gel process has been used to prepare anodic coatings on these supports at moderate thermal treatment temperature, in order to keep a good support mechanical behavior and limit metallic corrosion. Indeed, we take advantage of the numerous reaction routes that sol–gel method can offer to first synthesize NiO–YSZ (yttria-stabilized zirconia) homogeneous composites, and then to process films of different thicknesses on metallic supports by dipcoating. In this work, the metallic supports could be either dense or porous. To begin with, duplex microstructured anodes were prepared from both thin and thick layers, directly deposited on dense metallic supports. The interfacial anodic layer, around 100 nm thick, improves adhesion and accommodates stresses between metallic interconnect and active thick anode. Moreover, by dipping the substrate into an optimized slurry containing sol–gel composite powders, films of a few microns thick have been obtained and constituted the active anodic part. A heat treatment at only 800 °C leads to a coherent anodic duplex stacking which is continuous, homogeneous and adherent. Subsequently, thick anodic films have also been deposited on two different porous supports, with both dip-coating process and slurries routes. These thick anodic coatings were characterized after thermal treatment at 800 °C.

Item Type:Conference or Workshop Item (Paper)
Additional Information:This article is available at Elsevier editor. The definitive version is available at http://www.sciencedirect.com The original PDF of the article can be found at Surface and Coatings Technology website : http://www.sciencedirect.com/science/journal/02578972
HAL Id:hal-04030133
Audience (conference):International conference proceedings
Uncontrolled Keywords:
Institution:Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Laboratory name:
Deposited On:15 Jul 2010 15:35

Repository Staff Only: item control page