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Microfibrous TiO2 supported photocatalysts prepared by metal-organic chemical vapor infiltration for indoor air and waste water purification

Sarantopoulos, Christos and Puzenat, Eric and Guillard, Chantal and Herrmann, Jean-Marie and Gleizes, Alain and Maury, Francis Microfibrous TiO2 supported photocatalysts prepared by metal-organic chemical vapor infiltration for indoor air and waste water purification. (2009) Applied Catalysis B: Environmental, 91 (1-2). 225-233 . ISSN 0926-3373

(Document in English)

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Official URL: http://dx.doi.org/10.1016/j.apcatb.2009.05.029


The photocatalytic degradation of gaseous (toluene) and aqueous (imazapyr, malic acid, orange G) pollutants over TiO2 supported photocatalysts is investigated using a batch reactor. A strong influence of the microstructural characteristics of TiO2 on the decomposition kinetics of the pollutants is found. Well crystallized, porous TiO2-anatase films grown under low pressure at 400–500 8C by MOCVD on glass plates and by MOCVI on glass micro-fibers are the best heterogeneous photocatalysts, showing the highest activity. We demonstrate a good control of these characteristics by choosing the deposition parameters. Achieving conformal coverage (i.e. good infiltration) of glass micro-fibers by the TiO2 thin films has also a strong influence on the photocatalytic activity. A correlation between optimal infiltration, film microstructure and photocatalytic activity is established. Strong similarities between optimal photocatalytic decomposition rate in gas and liquid phase were found with respect to the film microstructure and the photocatalyst mass. The total mineralization of the toluene was prevented because of the deactivation of the photocatalyst surface. However the reactivation of the photocatalyst was achieved by UV irradiation under oxygen stream. This allows a long-term use of the photocatalyst.

Item Type:Article
Additional Information:Thanks to Elsevier editor. The definitive version is available at http://www.sciencedirect.com The original PDF of the article can be found at Applied Catalysis B: Environmental website : http://www.sciencedirect.com/science/journal/09263373
HAL Id:hal-00430907
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Other partners > Université Claude Bernard-Lyon I - UCBL (FRANCE)
Laboratory name:
Deposited On:13 Dec 2010 14:23

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