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Corrosion protection of AA2024 sealed anodic layers using the hydrophobic properties of carboxylic acids

Boisier, Grégory and Lamure, Alain and Pébère, Nadine and Portail, Nicolas and Villatte, Martine Corrosion protection of AA2024 sealed anodic layers using the hydrophobic properties of carboxylic acids. (2009) Surface and Coatings Technology, 203 (22). 3420-3426. ISSN 0257-8972

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Official URL: http://dx.doi.org/10.1016/j.surfcoat.2009.05.008


The present study investigates the use of carboxylic acids as a post-treatment for sealed AA2024 anodised in tartaric–sulphuric acid electrolyte. Four monocarboxylic acids with different carbon chain lengths were tested ((CH3–(CH2)n–COOH with n=4, 8, 12 and 16). Hydrophobic surface properties after the posttreatment were characterized by contact angle measurements. Electrochemical impedance spectroscopy (EIS) was performed to assess the ability of the four carboxylic acids to form protective films. It was shown that stearic acid (n=16) used in its pure molten state was the most efficient. The organic film formed very rapidly (under 5 min) and contributed to the enhancement of the protection in terms of corrosion resistance of the sealed anodic layers. EIS measurements showed the presence of the organic films on the specimen surface.

Item Type:Article
Additional Information:Thanks to Elsevier editor. The definitive version is available at http://www.sciencedirect.com The original PDF of the article can be found at Surface and Coatings Technology website :http://www.sciencedirect.com/science/journal/02578972
HAL Id:hal-03565798
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Other partners > EADS - Astrium (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Laboratory name:
Deposited On:08 Dec 2010 15:54

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