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Injection of vacancies at metal grain boundaries during the oxidation of nickel

Pérusin, Simon and Viguier, Bernard and Monceau, Daniel and Ressier, Laurence and Andrieu, Eric Injection of vacancies at metal grain boundaries during the oxidation of nickel. (2004) Acta Materialia, 52 (18). 5375-5380. ISSN 1359-6454

(Document in English)

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Official URL: http://dx.doi.org/10.1016/j.actamat.2004.07.043


Nickel foils have been oxidised at 1000 °C on one side only in laboratory air, the other side being protected from oxidation by a reducing atmosphere. After the oxidation treatment, the unoxidised face was carefully examined by using an atomic force microscope. Grain boundaries grooves were characterised and their depth were compared to the ones obtained on the same sample heat treated in the reducing atmosphere during the same time. Grain boundaries grooves are found to be much deeper in the case of the single side oxidised samples. It is shown that this additional grooving is directly linked to the growth of the oxide scale on the opposite side and that it can be explained by the diffusion of the vacancies produced at the oxide scale–metal interface, across the entire sample through grain boundaries. Moreover, the comparison between single side oxidised samples and samples oxidised on both sides points out that voids in grain boundaries are only observed in this latter case proving the vacancies condensation in the metal when the two faces are oxidised.

Item Type:Article
Additional Information:Thanks to Elsevier editor. The definitive version is available at http://www.sciencedirect.com The original PDF of the article can be found at Acta Materialia website : http://www.sciencedirect.com/science/journal/13596454
HAL Id:hal-03602350
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Université de Toulouse > Institut National des Sciences Appliquées de Toulouse - INSA (FRANCE)
French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Laboratory name:
Deposited On:01 Jul 2009 13:33

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