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Influence of Hybrid Sol-Gel Crosslinker on Self-Healing Properties for Multifunctional Coatings

Lollivier, Guillaume and Gressier, Marie and Ansart, Florence and Aufray, Maëlenn and Menu, Marie-Joëlle Influence of Hybrid Sol-Gel Crosslinker on Self-Healing Properties for Multifunctional Coatings. (2021) Materials, 14 (18). 5382. ISSN 1996-1944

(Document in English)

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Official URL: https://doi.org/10.3390/ma14185382


Self-healing polymers are a new class of material that has recently received a lot of attention because of the lifespan improvement it could bring to multiple applications. One of the major challenges is to obtain multifunctional materials which can self-heal and exhibit other interesting properties such as protection against corrosion. In this paper, the effect of the incorporation of an aminosilane on the properties of a self-healing organic polymer containing disulfide bond is studied on films and coatings for aluminium AA2024-T3 using simple one step in situ synthesis. Hybrid coatings with enhanced anticorrosion properties measured by EIS were obtained thanks to the formation of a protective oxide interface layer, while exhibiting wound closure after exposition at 75 °C. The thermal, mechanical and rheological properties of the films with different aminosilane amounts were characterized in order to understand the influence of the slight presence of the inorganic network. Stiffer and reprocessable hybrid films were obtained, capable to recover their mechanical properties after healing. The nanocomposite structure, confirmed by TEM, had a positive effect on the self-healing and stress relaxation properties. These results highlight the potential of sol-gel chemistry to obtain efficient anticorrosion and self-healing coatings.

Item Type:Article
HAL Id:hal-03714609
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Laboratory name:
Deposited On:05 Jul 2022 14:54

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