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Effect of size, concentration, and nature of fillers on crystallinity, thermal, and mechanical properties of polyetheretherketone composites

Doumeng, Marie and Berthet, Florentin and Delbé, Karl and Marsan, Olivier and Denape, Jean and Chabert, France Effect of size, concentration, and nature of fillers on crystallinity, thermal, and mechanical properties of polyetheretherketone composites. (2021) Journal of Applied Polymer Science. 1-19. ISSN 0021-8995

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Official URL: https://doi.org/10.1002/app.51574


Polyetheretherketone (PEEK) composites exhibit high stiffness, chemical stability, and heat resistance and they are therefore employed in applications under severe operating environments. This work aims to provide insight into the effect of the size, concentration, and type of fillers on the thermal and mechanical properties of PEEK. A total of 32 composites are used to highlight the influence of nature (lamellae, such as boron nitride and graphite and silicon carbide and alumina), size (nano and micrometric), and content (2.5, 5, 7.5, and 10 vol%) of fillers. The melting temperature and lamellar thickness did not change regardless of the nature of the filler. The thermomechanical analysis demonstrates that lamellar fillers form a percolating network and contribute significantly to the enhancement of the storage modulus. The increase in the storage modulus is proportional to the filler content, and it is more pronounced for micro composites. As expected, the percolating network is formed at lower concentrations for lamellar fillers than for spherical ones. The highest conductivity is achieved with graphite at 0.823 W/(m·K), which is twice that of PEEK for 10 vol%. Moreover, the use of micrometric fillers results in thermal conductivity enhancement attributed to the higher amount of efficient hot zones for heat transfer.

Item Type:Article
Additional Information:https://v2.sherpa.ac.uk/id/publication/15088
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Ecole nationale supérieure des Mines d'Albi-Carmaux - IMT Mines Albi (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Institut National des Sciences Appliquées de Toulouse - INSA (FRANCE)
Université de Toulouse > Institut Supérieur de l'Aéronautique et de l'Espace - ISAE-SUPAERO (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Laboratory name:
Occitanie region; Université de Toulouse
Deposited On:10 Sep 2021 12:57

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