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Electrodeposition of biphasic calcium phosphate coatings with improved dissolution properties

Drevet, Richard and Fauré, Joël and Sayen, Stéphanie and Marle-Spiess, Mélodie and El Btaouri, Hassan and Benhayoune, Hicham Electrodeposition of biphasic calcium phosphate coatings with improved dissolution properties. (2019) Materials Chemistry and Physics, 236. 121797. ISSN 0254-0584

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Official URL: https://doi.org/10.1016/j.matchemphys.2019.121797


Biphasic calcium phosphate coatings (hydroxyapatite/β-tricalcium phosphate) on titanium substrate (Ti6Al4V) are synthetized by pulsed current electrodeposition coupled to a thermal treatment under controlled atmosphere. The experimental conditions of the process such as the hydrogen peroxide amount and the treatment temperature are optimized in order to obtain different coatings compositions. The physico-chemical and structural characterizations of the coatings are carried out respectively by scanning electron microscopy associated with energy dispersive X-ray spectroscopy (SEM-EDXS) and X-ray diffraction (XRD). The in vitro dissolution-precipitation properties of the coated substrates are investigated by immersions into Dulbecco's Modified Eagle Medium (DMEM) from 1 to 28 days. The calcium and phosphorus concentrations variations in the biological liquid are assessed by Induced Coupled Plasma - Atomic Emission Spectroscopy (ICP-AES) for each immersion time. Furthermore, the corrosion behavior of the coated substrates are investigated using potentiodynamic polarization tests in DMEM and in Ringer's solution. The results show that this innovative process is suitable to synthesize two coatings composed respectively of HAP (37%)/β-TCP (63%) and HAP (62%)/β-TCP (38%) with different morphologies. On the other hand, the in vitro studies reveal that the coatings composition greatly influences their behavior in physiological medium, i.e. their dissolution-precipitation and their corrosion protection properties.

Item Type:Article
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Other partners > Institut de Chimie Moléculaire de Reims - ICMR (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Other partners > Université de Reims - Champagne-Ardenne (FRANCE)
Laboratory name:
Deposited On:07 May 2021 07:58

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