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Ultrafast Synthesis of Calcium Vanadate for Superior Aqueous Calcium-Ion Battery

Liu, Liyuan and Wu, Yih-Chyng and Rozier, Patrick and Taberna, Pierre-Louis and Simon, Patrice Ultrafast Synthesis of Calcium Vanadate for Superior Aqueous Calcium-Ion Battery. (2019) Research, 2019. 1-11. ISSN 2639-5274

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Official URL: https://doi.org/10.34133/2019/6585686

Abstract

Recently, multivalent aqueous calcium-ion batteries (CIBs) have attracted considerable attention as a possible alternative to Li-ion batteries. However, traditional Ca-ion storage materials show either limited rate capabilities and poor cycle life or insufficient specific capacity. Here, we tackle these limitations by exploring materials having a large interlayer distance to achieve decent specific capacities and one-dimensional architecture with adequate Ca-ion passages that enable rapid reversible (de)intercalation processes. In this work, we report the high-yield, rapid, and low-cost synthesis of 1D metal oxides MV3O8 (M=Li, K), CaV2O6, and CaV6O16·7H2O (CVO) via a molten salt method. Firstly, using 1D CVO as electrode materials, we show high capacity 205 mA h g-1, long cycle life (>97% capacity retention after 200 cycles at 3.0 C), and high-rate performance (117 mA h g-1 at 12 C) for Ca-ion (de)intercalation. This work represents a step forward for the development of the molten salt method to synthesize nanomaterials and to help pave the way for the future growth of Ca-ion batteries.

Item Type:Article
HAL Id:hal-03050839
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Other partners > Collège de France (FRANCE)
Other partners > Ecole Nationale Supérieure de Chimie de Paris - ENSCP (FRANCE)
Other partners > Ecole Nationale Supérieure de Chimie de Montpellier - ENSCM (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Other partners > Institut polytechnique de Grenoble (FRANCE)
Other partners > Université Paris Sciences & Lettres - PSL (FRANCE)
Other partners > Sorbonne Université (FRANCE)
Other partners > Université Grenoble Alpes - UGA (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Other partners > Université de Nantes (FRANCE)
Other partners > Université de Picardie Jules Verne (FRANCE)
Other partners > Université de Pau et des Pays de l'Adour - UPPA (FRANCE)
Other partners > Université de Haute Alsace - UHA (FRANCE)
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Deposited On:10 Dec 2020 09:32

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