OATAO - Open Archive Toulouse Archive Ouverte Open Access Week

Magnetoelectric coupling in PVDF/Nano NaNbO3/NanoNi composites: Influence of Ni particles aspect ratio

Martin, Baptiste and Dantras, Eric and Lonjon, Antoine and Lacabanne, Colette and Laffont, Lydia Magnetoelectric coupling in PVDF/Nano NaNbO3/NanoNi composites: Influence of Ni particles aspect ratio. (2020) IEEE Transactions on Dielectrics and Electrical Insulation, 27 (5). 1381-1386. ISSN 1070-9878

(Document in English)

PDF (Author's version) - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader

Official URL: https://doi.org/10.1109/TDEI.2020.008432


In this work, three phase magnetoelectric nanocomposites are successfully prepared by solvent casting from α-PVDF. The extrinsic piezoelectric effect is insured by 20 vol% of NaNbO 3 ferroelectric nanoparticles prepared by the hydrothermal process. Nickel is chosen as the magnetic phase. In order to maintain insulation, electrical percolation is avoided by using nickel contents lower than the percolation threshold. Two different morphologies are employed: spherical nanoparticles (NiNPs) and nanochains (NNCs) with an aspect ratio of 80. NNCs are obtained by a polyol process under a magnetic field. Thin films of nanocomposites are processed by hot pressing. The real part of the dielectric permittivity (ε') of composites is governed by Maxwell-Wagner-Sillars polarization at the PVDF/Ni interfaces. An important increase of ε' at low frequency is observed for PVDF/NaNbO 3 /NNCs composites; it favors the magnetoelectric coupling. Piezoelectric properties of composites are dependent upon mechanical modulus so that the most higher d 33 is obtained for PVDF / NaNbO 3 / NiNPs. Magnetoelectric coupling coefficient (α ME ) is determined from magnetoelectric intensity. PVDF / NaNbO 3 / NiNPs composites exhibit enhanced magnetoelectric coupling. The a ME coupling coefficient reaches 4.2V/(mOe). The magnetic properties are significantly improved by the NiNPs

Item Type:Article
HAL Id:hal-03165275
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Laboratory name:
Deposited On:06 Jan 2021 14:17

Repository Staff Only: item control page