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Synthesis and physical chemical characterizations of octacalcium phosphate–based biomaterials for hard-tissue regeneration

Rey, Christian and Combes, Christèle and Drouet, Christophe Synthesis and physical chemical characterizations of octacalcium phosphate–based biomaterials for hard-tissue regeneration. (2020) In: Octacalcium Phosphate Biomaterials. (Woodhead Publishing Series in Biomaterials). Woodhead Publishing, 177-212. ISBN 978-0-08-102511-6

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Official URL: https://doi.org/10.1016/B978-0-08-102511-6.00008-X


Several calcium phosphate compounds corresponding to the octacalcium phosphate (OCP) chemical composition are described. In addition to the triclinic pentahydrate structure, amorphous and apatitic OCPs have been synthesized, and their preparations and some of their physical–chemical properties are given. Other related phases, such as carbonated OCP, are discussed in relation with the characteristics of biological apatites, especially bone mineral. Biomimetic nanocrystalline apatites (BNAs) analogous to bone mineral regarding their composition, crystal shape, and specific feature, such as a surface-hydrated layer containing nonapatitic environments of the mineral ions, are presented. The correlations between this hydrated layer and the triclinic pentahydrate OCP are discussed, and the fragility of this structural feature is stressed. The determining role of carbonate ions in the evolution of BNA is shown and related to bone mineral and tooth enamel properties. The physical–chemical characterizations of these different compounds, using different techniques (chemical analyses, Fourier-transform infrared spectroscopy, X-ray diffraction, and solid-state nuclear magnetic resonance) are compared.

Item Type:Book Section
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
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Deposited On:07 Jul 2020 09:01

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