Mugnier, Emmanuelle and Barnabé, Antoine
and Tailhades, Philippe
Synthesis and characterization of CuFeO2+d delafossite powders.
(2006)
Solid State Ionics, 177 (5 - 6). 607-612. ISSN 0167-2738
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(Document in English)
PDF (Author's version) - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader 758kB |
Official URL: http://dx.doi.org/10.1016/j.ssi.2005.11.026
Abstract
Effects of oxygen off-stoichiometry have been investigated on CuFeO2+d delafossite-type powders prepared by solid state reaction. Materials annealed at different temperatures under air atmosphere were compared. Thermogravimetric analysis coupled with X-ray structural analysis showed that a powdered CuFeO2 can be oxidized up to CuFeO2+d with d =0.18. Electrical measurements confirm the existence of oxidized CuFeO2+d phases. Particular attention is paid to the correlation between oxidation process and phase stabilities in the CuFeO2 and copper spinel phase system.
Item Type: | Article |
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Additional Information: | Thanks to Elsevier editor. The definitive version is available at http://www.sciencedirect.com The original PDF of the article can be found at Solid State Ionics website : http://www.sciencedirect.com/science/journal/01672738 |
HAL Id: | hal-03596308 |
Audience (journal): | International peer-reviewed journal |
Uncontrolled Keywords: | |
Institution: | Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE) Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE) French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE) |
Laboratory name: | |
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Deposited On: | 26 May 2009 14:37 |
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