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Nanosized iron and iron–cobalt spinel oxides as catalysts for methanol decomposition

Manova, Elina and Tsoncheva, Tanya and Estournès, Claude and Paneva, Daniela and Tenchev, Krassimir and Mitov, Ivan and Petrov, L. Nanosized iron and iron–cobalt spinel oxides as catalysts for methanol decomposition. (2006) Applied Catalysis A General, 300 (2). 170-180. ISSN 0926-860X

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Official URL: http://dx.doi.org/10.1016/j.apcata.2005.11.005


Nanosized iron and mixed iron–cobalt oxides supported on activated carbon materials and their bulk analogues prepared by thermal synthesis are studied by X-rays diffraction, Mo¨ssbauer spectroscopy, magnetic measurements and temperature programmed reduction. Their catalytic behavior in methanol decomposition to H2, CO and methane is tested. Phase transformations in the metal oxides affected by the reaction medium are also investigated. Changes in the reaction mechanism of the methanol decomposition after the metal oxides deposition on the support as compared to the bulk phases are discussed.

Item Type:Article
Additional Information:Thanks to Elsevier editor. The definitive version is available at http://www.sciencedirect.com The original PDF of the article can be found at Applied Catalysis A General website : http://www.sciencedirect.com/science/journal/0926860X
HAL Id:hal-03597065
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:Other partners > Bulgarian Academy of Sciences (BULGARIA)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Laboratory name:
Deposited On:26 May 2009 08:50

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