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Tetraphenylphosphonium [2-(mercaptomethylcarbonylamino)-N-(2-methylaminophenyl)ethanamido(4-)-[kappa]4S,N,N',N'']oxorhenate(V)

Le Gal, Julien and Benoist, Eric and Gressier, Marie and Bélanger-Gariépy, Francine and Beauchamp, André L. Tetraphenylphosphonium [2-(mercaptomethylcarbonylamino)-N-(2-methylaminophenyl)ethanamido(4-)-[kappa]4S,N,N',N'']oxorhenate(V). (2007) Acta Crystallographica Section E, 63. m868-m869. ISSN 1600-5368

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Official URL: http://dx.doi.org/10.1107/S1600536807008070


The title compound, (C24H20P)[Re(C11H11N3O2S)O], is the [(C6H5)4P]+ salt of a square-pyramidal [ReOL]- complex anion [L is the deprotonated 2-(mercaptomethylcarbonylamino)-N-(2-methylaminophenyl)ethanamide ligand], in which the Re=O bond is apical and the tetradentate (N-N-N-S)4- ligand fills the four basal sites. The presence of a methyl group on the terminal N-atom donor induces a small displacement of the coordinated S atom.

Item Type:Article
Additional Information:Thanks to International Union of Crystallography editor. The definitive version is available at http://scripts.iucr.org The original PDF of the article can be found at Acta Crystallographica Section E website : http://journals.iucr.org/e/journalhomepage.html
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Other partners > Université de Montréal - UdeM (CANADA)
Laboratory name:
Deposited On:18 May 2009 12:58

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