OATAO - Open Archive Toulouse Archive Ouverte Open Access Week

Low-temperature molten salt synthesis and characterization of Cu2ZnSnS4 ultrafine powders

Benchikhi, Mohamed and Ouatib, Rachida El and Er-Rakho, Lahcen and Guillemet, Sophie and Demai, Jean-Jacques and Durand, Bernard Low-temperature molten salt synthesis and characterization of Cu2ZnSnS4 ultrafine powders. (2017) Optik, 138. 568-572. ISSN 0030-4026

(Document in English)

PDF (Author's version) - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader

Official URL: https://doi.org/10.1016/j.ijleo.2017.02.076


Nano-crystalline particles of Cu2ZnSnS4 have been successfully synthesized by a relatively low-temperature molten salt technique. The reaction of metal chlorides with KSCN at 400°C for 24h led to the Cu2ZnSnS4 phase. The phase purity of Cu2ZnSnS4 nanocrystals has been confirmed by X-ray diffraction and Raman spectroscopy. The morphology and the crystallite size were evaluated by scanning and transmission electron microscopies. The Cu2ZnSnS4 nanocrystals possess an optical band gap of 1.5eV, very close to the theoretical optimum for solar energy conversion.

Item Type:Article
HAL Id:hal-02392116
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Other partners > Université Hassan II Casablanca - UH2C (MOROCCO)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Laboratory name:
Volubilis Partenariat Hubert Curien - Centre national de la recherche scientifique - CNRS
Deposited On:03 Dec 2019 17:54

Repository Staff Only: item control page