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Improving ionic conductivity by Mg-doping of A2SnO3 (A=Li+, Na+)

Blazquez-Alcover, Ignacio and Rousse, Gwenaelle and Alves Dalla Corte, Daniel and Badot, Jean-Claude and Grimaud, Alexis and Rozier, Patrick and Tarascon, Jean-Marie Improving ionic conductivity by Mg-doping of A2SnO3 (A=Li+, Na+). (2017) Solid State Ionics, 308. 16-21. ISSN 0167-2738

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Official URL: https://doi.org/10.1016/j.ssi.2017.05.013

Abstract

The search for Li ions conducting ceramics is burgeoning, owing to the regain interest for solid state batteries. Here we investigate the effect of Mg substitutions on the ionic conductivity of the A2SnO3 (A=Li, Na) phases. Pure A1.8Mg0.1SnO3 and A2.2Mg0.1Sn0.9O3 were structurally characterized and their ionic conductivity was measured by AC impedance spectroscopy. We show a decrease of the activation energy with increasing the Mg substitution and found ionic conductivities three and two orders of magnitude higher for Li2.2Mg0.1Sn0.9O3 and Na1.8Mg0.1SnO3 as compared to pristine Li2SnO3 and Na2SnO3, respectively. Neutron diffraction was used to determine the Mg localization in the crystal structure and to provide a rationale for the ionic conductivity changes. Our results confirm the high sensitivity of the ionic conductivity on chemical substitutions, even limited ones.

Item Type:Article
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Other partners > Collège de France (FRANCE)
Other partners > Ecole Nationale Supérieure de Chimie de Paris - ENSCP (FRANCE)
Other partners > Ecole Nationale Supérieure de Chimie de Montpellier - ENSCM (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - INPT (FRANCE)
Other partners > Institut polytechnique de Grenoble (FRANCE)
Other partners > Sorbonne Université (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UPS (FRANCE)
Other partners > Université de Nantes (FRANCE)
Other partners > Université de Picardie Jules Verne (FRANCE)
Other partners > PSL Research University (FRANCE)
Other partners > Université de Pau et des Pays de l'Adour - UPPA (FRANCE)
Other partners > Université de Haute Alsace - UHA (FRANCE)
Other partners > Université de Montpellier (FRANCE)
Laboratory name:
Funders:
Réseau sur le Stockage Electrochimique de l'Energie - RS2E
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Deposited By: Yves MOMBOISSE
Deposited On:04 Dec 2019 12:17

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