Radjagobalou, Robbie
and Blanco, Jean-François and Dias da Silva Freitas, Victoria and Supplis, Caroline and Gros, Fabrice and Dechy-Cabaret, Odile and Loubière, Karine
A revised experimental protocol for implementing the actinometry method with the Reinecke’s salt.
(2019)
Journal of Photochemistry and Photobiology A: Chemistry, 382. 111934. ISSN 1010-6030
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(Document in English)
PDF (Author's version) - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader 508kB |
Official URL: https://doi.org/10.1016/j.jphotochem.2019.111934
Abstract
The present short note aims at proposing a revised experimental protocol to implement the actinometry method with Reinecke’s salt. It consists in substituting - for the dosing of the thiocyanate anions produced - perchloric acid (HClO4) by nitric acid (HNO3) - the latter being carefully chosen regarding the chemical equilibria occurring in the aqueous medium and the moderate risks of HNO3. This substitution has been rigorously validated by carrying out the experiments in a dedicated torus batch photoreactor enabling simple treatment of experimental results from a one-dimensional model.
| Item Type: | Article |
|---|---|
| HAL Id: | hal-02177175 |
| Audience (journal): | International peer-reviewed journal |
| Uncontrolled Keywords: | |
| Institution: | French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE) Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE) Other partners > Université Clermont Auvergne - UCA (FRANCE) Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE) Other partners > SIGMA Clermont (FRANCE) |
| Laboratory name: | |
| Statistics: | download |
| Deposited On: | 05 Jul 2019 10:39 |
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