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Synthesis of new cellulose ethers using Suzuki–Miyaura reactions

Goncalves, Cédric and Favre, Camille and Feuardant, Pierre and Klein, Sarah and Vaca-Garcia, Carlos and Cecutti, Marie-Christine and Thiebaud-Roux, Sophie and Vedrenne, Emeline Synthesis of new cellulose ethers using Suzuki–Miyaura reactions. (2015) Carbohydrate Polymers, 116. 51-59. ISSN 0144-8617

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Official URL: https://doi.org/10.1016/j.carbpol.2014.03.089

Abstract

Cellulose ethers are functionalized biopolymers that are industrially produced through drastic conditions employing gaseous reactants with a high risk of industrial accident. The cellulose ethers that are commercially available generally bear short carbon-chains. In this work, an alternative method using non-gaseous chemicals is proposed. It relies on the use of the Suzuki–Miyaura reaction employing mild, moisture- and air-stable conditions. Relatively innocuous reagents are used for this step, which allows the formation of a wide range of cellulose ethers bearing various functional groups with different chain-length.

Item Type:Article
HAL Id:hal-02064857
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
French research institutions > Institut National de la Recherche Agronomique - INRA (FRANCE)
Other partners > King Abdulaziz University - KAU (SAUDI ARABIA)
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Deposited On:12 Mar 2019 10:31

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