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Influence of water on the dissolution of cellulose in selected ionic liquids

Mazza, Mathieu and Catana, Dan-Andrei and Vaca-Garcia, Carlos and Cecutti, Marie-Christine Influence of water on the dissolution of cellulose in selected ionic liquids. (2009) Cellulose, 16 (2). 207-215. ISSN 0969-0239

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Official URL: https://doi.org/10.1007/s10570-008-9257-x

Abstract

Cellulose (7% water) was thoroughly dispersed in various ionic liquids (IL) and the turbidity of the mixture was investigated to distinguish real dissolution from fine dispersion. The dissolving ability of 1-butyl-3-methylimidazolium chloride (BMIMCl know cellulose solvent) and 11 other commercial IL (not reported as cellulose solvents) was studied. From the latter, only 1,3-dimethylimidazolium dimethylphosphate (DMIMDMP) could dissolve cellulose. The influence of water content on the real dissolution of cellulose in these two IL was investigated. The maximum theoretical amount of dissolved anhydrous cellulose in the IL was determined by extrapolation methodology at different temperatures. For cellulose in BMIMCl, it was 8.75 g/100 g of IL at 95 °C. DMIMDMP could achieve real cellulose dissolution only in a practically anhydrous system (2.3 g/100 g of IL at 30 °C) but dissolution was physically limited by high viscosity.

Item Type:Article
HAL Id:hal-02067524
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
French research institutions > Institut National de la Recherche Agronomique - INRA (FRANCE)
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Deposited On:14 Mar 2019 10:52

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