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Nanostructured thermosets from ionic liquid building block–epoxy prepolymer mixtures

Livi, Sébastien and Silva, Adriana A. and Thimont, Yohann and Nguyen, Thi Khanh Ly and Soares, Bluma G. and Gerard, Jean-François and Duchet-Rumeau, Jannick Nanostructured thermosets from ionic liquid building block–epoxy prepolymer mixtures. (2014) RSC Advances, 4 (53). 28099-28106. ISSN 2046-2069

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Official URL: https://doi.org/10.1039/C4RA03643C


Ionic liquids based on trihexyl(tetradecyl)phosphonium combined with dicyanamide counteranion were used for the first time as functional additives to achieve epoxy networked polymeric materials which display a structuration at nanoscale (20–30 nm) with dramatic mechanical properties and a higher thermal stability (>400 °C). In fact, the curing process was studied by FTIR, DSC highlighting an increase of the conversion epoxide groups in function of the IL amount (5–30 phr) and the morphology has been revealed by transmission electronic microscopy (TEM) and atomic force microscopy (AFM).

Item Type:Article
HAL Id:hal-01019123
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Other partners > Ecole Nationale Supérieure d'Ingénieurs de Caen - ENSICAEN (FRANCE)
Other partners > Institut National des Sciences Appliquées de Lyon - INSA (FRANCE)
Other partners > Universidade Federal do Rio de Janeiro - UFRJ (BRAZIL)
Other partners > Université de Caen Basse-Normandie (FRANCE)
Other partners > Université Claude Bernard-Lyon I - UCBL (FRANCE)
Other partners > Université Jean Monnet - St Etienne (FRANCE)
Other partners > Université de Lyon - UDL (FRANCE)
Laboratory name:
Deposited On:27 Mar 2019 08:35

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