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Ultra-fast precipitation of transient amorphous cerium oxalate in concentrated nitric acid media

Rodríguez-Ruiz, Isaac and Charton, Sophie and Radajewski, Dimitri and Bizien, Thomas and Teychené, Sébastien Ultra-fast precipitation of transient amorphous cerium oxalate in concentrated nitric acid media. (2018) CrystEngComm, 20 (24). 3302-3307. ISSN 1466-8033

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Official URL: https://doi.org/10.1039/c8ce00358k

Abstract

Amorphous cerium oxalate is characterized and reported here for the first time as a primary nucleating transient precursor for a more stable crystalline hydrated phase, at high supersaturation and in strong acid solutions. Preliminary results point out an initial binodal phase separation leading to precipitation.

Item Type:Article
HAL Id:hal-02305518
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Commissariat à l'Energie Atomique et aux énergies alternatives - CEA (FRANCE)
French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
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Deposited On:04 Oct 2019 09:45

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