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UV-cured polysulfone-based membranes: Effect of co-solvent addition and evaporation process on membrane morphology and SRNF performance

Altun, Veysi and Remigy, Jean-Christophe and Vankelecom, Ivo F.J. UV-cured polysulfone-based membranes: Effect of co-solvent addition and evaporation process on membrane morphology and SRNF performance. (2017) Journal of Membrane Science, 524. 729-737. ISSN 0376-7388

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Official URL: https://doi.org/10.1016/j.memsci.2016.11.060


Membranes consisting of a semi-interpenetrating network of polysulfone (PSU) and cross-linked polyacrylate were synthesized via non-solvent induced phase inversion followed by UV-treatment. Tetrahydrofuran (THF) or 1,4-dioxane (DIO) was added as co-solvent to the N,N-dimethylformamide (DMF)-based polymer solutions and cast films were subjected to evaporation prior to coagulation. Effects of synthesis variables on the membrane morphology and solvent resistant nanofiltration (SRNF) performance were investigated by using a Rose Bengal solution in isopropanol. By increasing the evaporation time from 0 to 100 s for the membranes prepared with THF and DIO as co-solvent respectively, rejections increased from 65.3% to 94.2% and 60.1–89.1%, while permeances decreased from 0.29 to 0.01 l/m2 h bar and 0.41–0.08 l/m2 h bar. A similar effect was observed when the co-solvent/solvent ratio was increased from 0/100 to 100/0: rejections increased from 63.1% to 94.9% and 59.2–90.6%, while permeances decreased from 0.43 to 0.01 l/m2 h bar for THF-based membranes and to 0.07 l/m2 h bar for DIO-based membranes respectively. A post-treatment was performed to increase the flux by immersing UV-cured PSU-based films in DMF for 48 h. The resultant membranes showed higher permeances and lower rejections, making them especially useful as potential candidates for stable supports to apply selective layers upon, such as e.g. in thin film composite (TFC) membranes. As observed in scanning electron microscopy, higher evaporation times and lower initial co-solvent concentrations resulted in less or even no macrovoids.

Item Type:Article
HAL Id:hal-01882541
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Other partners > Katholieke Universiteit Leuven - KU LEUVEN (BELGIUM)
Laboratory name:
Deposited On:27 Sep 2018 08:34

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