Gibilaro, Mathieu and Massot, Laurent
and Chamelot, Pierre
Thermodynamic properties determination in LiF-CaF 2 using electrochemistry in high temperature fused salts: application to CeF 3.
(2017)
Journal of The Electrochemical Society, 164 (12). 307-311. ISSN 0013-4651
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(Document in English)
PDF (Author's version) - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader 592kB |
Official URL: https://doi.org/10.1149/2.0691712jes
Abstract
Combining thermodynamic database and electrochemical measurements, CeF3 thermodynamics properties were determined between 1113 K and 1233 K in LiF-CaF2 solution. First, standard potentials of CeF3/Ce were calculated in different reference states: liquid and solid, and infinite dilution. Then activity coefficients of CeF3 were estimated in the different reference states and for different composition scales: molarity, molality and molar fraction. Finally, constants which interconnected the infinite dilution reference state and the solid and liquid reference states were evaluated.
Item Type: | Article |
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HAL Id: | hal-02134835 |
Audience (journal): | International peer-reviewed journal |
Uncontrolled Keywords: | |
Institution: | French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE) Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE) Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE) |
Laboratory name: | |
Statistics: | download |
Deposited On: | 08 Oct 2018 08:22 |
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