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Synthesis of yttria by aqueous sol-gel route to develop anti-CMAS coatings for the protection of EBPVD thermal barriers

Delon, Elodie and Ansart, Florence and Duluard, Sandrine Nathalie and Bonino, Jean-Pierre and Malié, André and Joulia, Aurélien and Gomez, Philippe Synthesis of yttria by aqueous sol-gel route to develop anti-CMAS coatings for the protection of EBPVD thermal barriers. (2016) Ceramics International, 42 (12). 13704-13714. ISSN 0272-8842

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Official URL: https://doi.org/10.1016/j.ceramint.2016.05.169


Anti-CMAS yttria coatings have been prepared by sol-gel routes. Yttria powders with controlled morphology are prepared via auto-combustion of yttrium precursors in a polymerized matrix. The influence of key parameters of the water-based sols is assessed. Indeed, the pH of the initial sol and the temperature of thermal treatment play a major role in the morphology and grain size of yttria powders. To prevent infiltration of CMAS, yttria powders are proposed to be synthesized at pH=1 of the aqueous sol, with drying of the sol and heating at 900 °C. After optimization of the synthesis and deposition conditions via sol-gel route, yttria-based coatings with high specific surface area are obtained. They promote the interaction with melt CMAS and consequently limit the degradation of the thermal barrier coatings situated underneath. It was proved that anti-CMAS yttria coating is effective against the infiltration of CMAS at 1250 °C for 15 min and even 1 h.

Item Type:Article
Additional Information:Thanks to Elsevier editor. The definitive version is available at : https://www.sciencedirect.com/science/article/pii/S0272884216307891
HAL Id:hal-03515008
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Other partners > Direction Générale pour l'Armement - DGA (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Other partners > SAFRAN (FRANCE)
Other partners > Société nationale d'étude et de constructions de moteurs d'avion - SNECMA (FRANCE)
Laboratory name:
Deposited On:29 Mar 2018 13:13

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