OATAO - Open Archive Toulouse Archive Ouverte Open Access Week

Internal oxidation in dry and wet conditions for oxygen permeability of Fe–Ni alloys at 1150 and 1100 °C

Prillieux, Aurélien and Jullian, Domingo and Zhang, Jianqiang and Monceau, Daniel and Young, David J. Internal oxidation in dry and wet conditions for oxygen permeability of Fe–Ni alloys at 1150 and 1100 °C. (2017) Oxidation of Metals, 87 (3-4). 273-283. ISSN 0030-770X

(Document in English)

PDF (Author's version) - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader

Official URL: http://dx.doi.org/10.1007/s11085-017-9724-6


The design of new austenitic alloys based on the Fe–Ni–Cr system requires knowledge of their oxygen permeability. Data are available for pure Fe and Ni but not for Fe–Ni alloys. Wagner’s model for internal oxidation is used to evaluate the oxygen permeability in Fe–Ni alloys. Internal oxidation of Fe–Ni–Cr alloys carried out at 1150 and 1100 °C in Rhines packs and H2/H2O mixtures is described. Internal oxidation produces zones of FeCr2O4 and Cr2O3 precipitates, according to parabolic kinetics. Permeabilities are deduced taking into account interfacial diffusion contributions. Oxygen permeability decreases with nickel addition in a non-ideal way, and oxygen permeability in nickel-rich alloys is independent of the studied environments. However, the oxygen permeability in iron at the highest temperature studied is increased in H2/H2O.

Item Type:Article
Additional Information:Thanks to Springer Verlag editor. The original PDF of the article can be found at https://link.springer.com/article/10.1007%2Fs11085-017-9724-6
HAL Id:hal-01579032
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Other partners > University of New South Wales - UNSW (AUSTRALIA)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Laboratory name:
Australian Research Council - ARC
Deposited On:30 Aug 2017 08:51

Repository Staff Only: item control page