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Oxygen permeability of Fe-Ni-Cr alloys at 1100 and 1150 °C under carbon-free and carbon-containing gases

Jullian, Domingo and Prillieux, Aurélien and Zhang, Jianqiang and Young, David J. Oxygen permeability of Fe-Ni-Cr alloys at 1100 and 1150 °C under carbon-free and carbon-containing gases. (2016) Materials and Corrosion / Werkstoffe und Korrosion, 68 (2). 197-204. ISSN 0947-5117

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Official URL: https://doi.org/10.1002/maco.201508803


Wagner's model of internal oxidation allows the prediction of an alloy's critical concentration of oxide forming metal required to achieve a protective oxide scale at high temperatures. The model depends on oxygen permeability in the alloy, but this parameter has not been evaluated for the Fe-Ni system, and the influence of carbon-bearing gases is unknown. Oxygen permeability measurement by internal oxidation of Fe-Ni-Cr alloys, reacted at 1100 and 1150 8C is described. Exposures in Rhines packs and flowing CO-CO2 gas mixtures serve to assess the influence of carbon on oxygen permeability at the Fe-FeO equilibrium oxygen potential. Oxygen permeability in Fe-Ni increases with iron content in a non-ideal manner in both gas environments. Higher permeability is found in carbon bearing gases for iron-rich alloys, and the size of this effect increases with temperature.

Item Type:Article
HAL Id:hal-02003007
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Other partners > University of Sydney (AUSTRALIA)
Laboratory name:
Deposited On:01 Feb 2019 08:19

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