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Design of Fe3–xO4 raspberry decorated graphene nanocomposites with high performances in lithium-ion battery

Gerber, Olivier and Bégin-Colin, Sylvie and Pichon, Benoit P. and Barraud, Elodie and Lemonnier, Sébastien and Pham-Huu, Cuong and Daffos, Barbara and Simon, Patrice and Come, Jérémy and Bégin, Dominique Design of Fe3–xO4 raspberry decorated graphene nanocomposites with high performances in lithium-ion battery. (2016) Journal of Energy Chemisty, 25 (2). 272-277. ISSN 2095-4956

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Official URL: http://dx.doi.org/10.1016/j.jechem.2016.01.021


Fe3–xO4 raspberry shaped nanostructures/graphene nanocomposites were synthesized by a one-step polyol-solvothermal method to be tested as electrode materials for Li-ion battery (LIB). Indeed, Fe3–xO4 raspberry shaped nanostructures consist of original oriented aggregates of Fe3–xO4 magnetite nanocrystals, ensuring a low oxidation state of magnetite and a hollow and porous structure, which has been easily combined with graphene sheets. The resulting nanocomposite powder displays a very homogeneous spatial distribution of Fe3–xO4 nanostructures at the surface of the graphene sheets. These original nanostructures and their strong interaction with the graphene sheets resulted in very small capacity fading upon Li+ ion intercalation. Reversible capacity, as high as 660 mAh/g, makes this material promising for anode in Li-ion batteries application.

Item Type:Article
HAL Id:hal-01466430
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Other partners > Université de Strasbourg - UNISTRA (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Other partners > Institut franco-allemand de recherches de Saint-Louis - ISL (FRANCE)
Laboratory name:
Deposited On:13 Feb 2017 14:20

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