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Experimental Characterization and Population Balance Modelling of the Dense Silica Suspensions Aggregation Process.

Tourbin, Mallorie and Frances, Christine Experimental Characterization and Population Balance Modelling of the Dense Silica Suspensions Aggregation Process. (2008) Chemical Engineering Science, 63 (21). 5239 -5251. ISSN 0009-2509

(Document in English)

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Official URL: http://dx.doi.org/10.1016/j.ces.2008.06.028


Concentrated suspensions of nanoparticles subjected to transport or shear forces are commonly encountered in many processes where particles are likely to undergo processes of aggregation and fragmentation under physico-chemical interactions and hydrodynamic forces. This study is focused on the analysis of the behavior of colloidal silica in dense suspensions subjected to hydrodynamic forces in conditions of destabilization. A colloidal silica suspension of particles with an initial size of about 80 nm was used. The silica suspension concentration was varied between 3% and 20% of weight. The phenomenon of aggregation was observed in the absence of any other process such as precipitation and the destabilization of the colloidal suspensions was obtained by adding sodium chloride salt. The experiments were performed in a batch agitated vessel. The evolution of the particle size distributions versus time during the process of aggregation was particularly followed on-line by acoustic spectroscopy in dense conditions. Samples were also analyzed after an appropriate dilution by laser diffraction. The results show the different stages of the silica aggregation process whose kinetic rates depend either on physico-chemical parameters or on hydrodynamic conditions. Then, the study is completed by a numerical study based on the population balance approach. By the fixed pivot technique of Kumar and Ramkrishna [1996. On the solution of population balance equations by discretization—I. A fixed pivot technique. Chemical Engineering Science 51 (8), 1311–1332], the hypothesis on the mechanisms of the aggregation and breakage processes were justified. Finally, it allows a better understanding of the mechanisms of the aggregation process under flowing conditions.

Item Type:Article
Additional Information:Thanks to Elsevier editor. The definitive version is available at http://www.sciencedirect.com The original PDF of the article can be found at Chemical Engineering Science website : http://www.sciencedirect.com/science/journal/00092509
HAL Id:hal-00475990
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Laboratory name:
Laboratoire de Génie Chimique - LGC (Toulouse, France) - Génie des Interfaces & Milieux Divisés (GIMD)
Deposited On:12 Nov 2008 10:52

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