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Flash-Point prediction for binary partially miscible aqueous-organic mixtures

Liaw, Horng-Jang and Chen, Chien Tsun and Gerbaud, Vincent Flash-Point prediction for binary partially miscible aqueous-organic mixtures. (2008) Chemical Engineering Science, 6 (18). 4543-4554. ISSN 0009-2509

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Official URL: http://dx.doi.org/10.1016/j.ces.2008.06.005


Flash point is the most important variable used to characterize fire and explosion hazard of liquids. Herein, partially miscible mixtures are presented within the context of liquid-liquid extraction processes and heterogeneous distillation processes. This paper describes development of a model for predicting the flash point of binary partially miscible mixtures of aqueous-organic system. To confirm the predictive efficiency of the derived flash points, the model was verified by comparing the predicted values with the experimental data for the studied mixtures: water + 1-butanol; water + 2-butanol; water + isobutanol; water + 1-pentanol; and, water + octane. Results reveal that immiscibility in the two liquid phases should not be ignored in the prediction of flash point. Overall, the predictive results of this proposed model describe the experimental data well when using the LLE and VLE parameters to estimate sequentially the span of two liquid phases and the flash point, respectively. Potential application for the model concerns the assessment of fire and explosion hazards, and the development of inherently safer designs for chemical processes containing binary partially miscible mixtures of aqueous-organic system.

Item Type:Article
Additional Information:This publication is available on http://www.sciencedirect.com/science/journal/00092509
HAL Id:hal-03580226
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:Other partners > China Medical University (TAIWAN)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Laboratory name:
Department of occupational safety and health (Taichung,Taiwan) - -
Laboratoire de Génie Chimique - LGC (Toulouse, France) - Procédés Systèmes Industriels (PSI) - Analyse fonctionnelle des Procédés
Deposited On:20 Jan 2009 15:11

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