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Molecular mobility in piezoelectric hybrid nanocomposites with 0–3 connectivity: Volume fraction influence

Capsal, Jean-Fabien and Dantras, Eric and Dandurand, Jany and Lacabanne, Colette Molecular mobility in piezoelectric hybrid nanocomposites with 0–3 connectivity: Volume fraction influence. (2011) Journal of Non-Crystalline Solids, 357 (19-20). 3410-3415. ISSN 0022-3093

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Official URL: http://dx.doi.org/10.1016/j.jnoncrysol.2011.06.009


ThermoStimulated Current and Dynamic Dielectric Spectroscopy studieswere carried out on hybrid ferroelectric Polyamide 11/Barium Titanate to investigate dielectric relaxationmodes. The correlated results obtained by both methods allow us to describe precisely the molecular mobility of this 0–3 nanocomposite; in this work we will focus on the influence of the 700 nm nanoparticles volume fraction. The dielectric spectroscopy shows that the molecularmobility associatedwith the liquid dynamic is not influenced by the volume fraction. The evolution of lowfrequency relaxation, observed by depolarization currents techniques, have been attributed to the decrease of Cooperative Rearranging Region size and the increase of intra/inter macromolecular interactions in the soft amorphous phase.

Item Type:Article
Additional Information:Thanks to Elsevier editor. The definitive version is available at http://www.sciencedirect.com The original PDF of the article can be found at Journal of Non-Crystalline Solids website : http://www.sciencedirect.com/science/journal/00223093
HAL Id:hal-01162804
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:Other partners > Arkema (FRANCE)
French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Laboratory name:
Deposited On:11 Jun 2015 12:08

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