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ZnO-based varistors prepared by spark plasma sintering

Beynet, Yannick and Izoulet, Antoine and Guillemet-Fritsch, Sophie and Chevallier, Geoffroy and Bley, Vincent and Pérel, Thomas and Malpiece, Frédéric and Morel, Jonathan and Estournès, Claude ZnO-based varistors prepared by spark plasma sintering. (2015) Journal of the European Ceramic Society, 35 (4). 1199-1208. ISSN 0955-2219

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Official URL: http://dx.doi.org/10.1016/j.jeurceramsoc.2014.10.007


Varistor ceramics were prepared by spark plasma sintering (SPS) using two doped zinc oxide based powders. Optimized sintering cycle for the commercial powder (mixture of oxides) yielded dense parts (>99%) containing mainly ZnO grains (1 mm) and additional Bi2O3 and Zn7Sb2O12 oxides. Sintering at the low oxygen partial pressure inherent to SPS leads to the reduction of Bi2O3 into metallic Bi. To reduce the grain size, improve the distribution of dopants and the grain size distribution, we used co-precipitation to synthesize a powder with the same formulation as the commercial powder. Due to the high reactivity of this powder, fully dense parts were obtained at temperature as low as 400 ◦C under air atmosphere using carbide tools. Such conditions led to limited ZnO grain growth and bismuth reduction during the thermal cycle. The fine microstructure obtained led to varistances with to high electrical properties (threshold field higher than 2300 V/mm).

Item Type:Article
Additional Information:Thanks to Elsevier editor. The definitive version is available at http://www.sciencedirect.com/science/article/pii/S0955221914005421
HAL Id:hal-01168805
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Other partners > TRIDELTA (GERMANY)
Laboratory name:
Deposited On:26 Jun 2015 13:25

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