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Influence of anthropogenic inputs and a high-magnitude flood event on metal contamination pattern in surface bottom sediments from the Deba River urban catchment

Martínez-Santos, Miren and Probst, Anne and García-García, Jon and Ruiz-Romera, Estilita Influence of anthropogenic inputs and a high-magnitude flood event on metal contamination pattern in surface bottom sediments from the Deba River urban catchment. (2015) Science of the Total Environment, 514. 10-25. ISSN 0048-9697

(Document in English)

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Official URL: http://dx.doi.org/10.1016/j.scitotenv.2015.01.078


The purpose of this study was to assess the influence of anthropogenic factors (infrastructure construction and industrial and wastewater inputs) and hydrological factors (high-magnitude flood events) on metal and organic contamination and on the source variability of sediments taken from the Deba River and its tributaries. The pollution status was evaluated using a sequential extraction procedure (BCR 701), enrichment factor, individual and global contamination factors and a number of statistical analysis methods. Zn, Cu and Cr were found to have significant input from anthropogenic sources, with moderately severe enrichment, together with an extremely high potential risk of contamination. The principal scavenger of Cu and Cr was organic matter, whereas Zn was uniformly distributed among all non-residual fractions. For Fe, the anthropogenic contribution was more obviously detected in bulk sediments (b2 mm) than in fine fractions (b63 μm). Finally, the recent construction of a rail tunnel traversing Wealden Facies evaporites, together with intense rainfalls, was the main reason for the change in the source variability of bottom sediments and metal distribution in headwaters. The occurrence of a high-magnitude flood event resulted in a washout of the river bed and led to a general decrease in finegrained sediment and metal concentrations in labile fractions of channel-bottom sediments, and a consequent downstream transfer of the pollution.

Item Type:Article
Additional Information:Thanks to Elsevier editor. The definitive version is available at http://www.sciencedirect.com The original PDF of the article can be found at Science of the Total Environment website : http://www.sciencedirect.com/science/journal/00489697
HAL Id:hal-01113080
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Other partners > Universidad del País Vasco - Euskal Herriko Unibertsitatea - EHU (SPAIN)
Laboratory name:
Spanish Ministry of Science and Innovation (project CGL2011-26236) - the Basque Government (Consolidated Group of Hydrogeology and Environment, IT598-13) - Gipuzkoa Provincial Council (1-RR-3/12) - University of the Basque Country UPV-EHU (UFI11/26)
Deposited On:04 Feb 2015 12:43

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