OATAO - Open Archive Toulouse Archive Ouverte Open Access Week

Ex situ mineral carbonation for CO2 mitigation: Evaluation of mining waste resources, aqueous carbonation processability and life cycle assessment (Carmex project)

Bodénan, Françoise and Bourgeois, Florent and Petiot, Charlotte and Augé, Thierry and Bonfils, Benjamin and Julcour-Lebigue, Carine and Guyot, François and Boukary, Aissa and Tremosa, Joachim and Lassin, Arnault and Gaucher, Eric and Chiquet, Pierre Ex situ mineral carbonation for CO2 mitigation: Evaluation of mining waste resources, aqueous carbonation processability and life cycle assessment (Carmex project). (2014) Minerals Engineering, 59. 52-63. ISSN 0892-6875

(Document in English)

PDF (Author's version) - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader

Official URL: http://dx.doi.org/10.1016/j.mineng.2014.01.011


This article presents the main outputs from the multidisciplinary Carmex project (2009–2012), which was concerned with the possibility of applying ex situ mineral carbonation concepts to mafic/ultramafic mining wastes. Focus points of the project included (i) matching significant and accessible mining wastes to large CO2 emitters through a dedicated geographical information system (GIS), (ii) analysis of aqueous carbonation mechanisms of mining waste and process development and (iii) environmental assessment of ex situ mining waste carbonation through life cycle assessment (LCA) methodology. With a number of materials associated with the mining sector, the project took a close look at the aqueous carbonation mechanisms for these materials and obtained unexpected carbonation levels (up to 80%) by coupling mechanical exfoliation and reactive carbonation. Results from this work support the possibility of processing serpentine-rich peridotites without applying the classical first step of heat activation. Perspectives are also given for the carbonation of Ni-pyrometallurgical slag available closed to ultramafic mining residues. LCA of the mining waste carbonation system as a whole made it clear that the viability of this CO2 storage option lies with the carbonation process itself and optimisation of its operating conditions. By combining the body of knowledge acquired by this project, it is concluded that New Caledonia, with its insularity and local abundance of ‘carbonable’ rocks and industrial wastes coupled with significant greenhouse gas (GHG) emissions from world-class nickel pyro and hydrometallurgical industries stands out as a strong potential candidate for application of ex situ mineral carbonation.

Item Type:Article
Additional Information:Thanks to Elsevier editor. The definitive version is available at http://www.sciencedirect.com/science/article/pii/S0892687514000120
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:Other partners > Bio Intelligence Service - Bio-IS (FRANCE)
French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Other partners > Institut de Physique du Globe de Paris - IPGP (FRANCE)
Other partners > Total (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
French research institutions > Bureau de Recherches Géologiques et Minières - BRGM (FRANCE)
Laboratory name:
French National Research Agency (ANR – CO2 Capture and Storage programme), Total (thesis funding)
Deposited On:13 Jun 2014 12:09

Repository Staff Only: item control page