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Microfluidic synthesis and assembly of reactive polymer beads to form new structured polymer materials

Berton, Nicolas and Serra, Christophe and Bouquey, Michel and Prat, Laurent E. and Hadziioannou, Georges Microfluidic synthesis and assembly of reactive polymer beads to form new structured polymer materials. (2008) Chemical Engineering Journal, 1 (suppl.). S93-S98. ISSN 1385-8947

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Official URL: http://dx.doi.org/10.1016/j.cej.2007.07.043


Monodisperse and size-controlled polymer particles were produced without surfactant or wash-coat from O/W monomer emulsions and ‘‘on the fly’’ polymerization under UV irradiation in a very simple needle/tubing system. The effect of the viscosity of the continuous phase on the size of final particles was investigated. The capillary number ratio was found to be relevant to predict the size of the droplets. A relation between dimensionless numbers predicts particle diameter as a function of the needle inner diameter and both velocity and viscosity ratios of continuous and dispersed phases. A functional comonomer was incorporated in the monomer phase so as to obtain polymer microparticles bearing reactive groups on their surface. Polymer beads necklaces were thus formed by linking polymer particles together.

Item Type:Article
Additional Information:This publication is available on http://www.sciencedirect.com/science/journal/13858947
HAL Id:hal-00467130
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Other partners > Université Louis Pasteur-Strasbourg I - ULP (FRANCE)
Laboratory name:
Deposited On:15 Oct 2008 09:34

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