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A General Approach for Predicting the Filtration of Soft and Permeable Colloids: The Milk Example

Bouchoux, Antoine and Qu, Peng and Bacchin, Patrice and Gésan-Guiziou, Geneviève A General Approach for Predicting the Filtration of Soft and Permeable Colloids: The Milk Example. (2014) Langmuir, 30 (1). 22-34. ISSN 0743-7463

(Document in English)

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Official URL: http://dx.doi.org/10.1021/la402865p


Membrane filtration operations (ultra-, microfiltration) are now extensively used for concentrating or separating an ever-growing variety of colloidal dispersions. However, the phenomena that determine the efficiency of these operations are not yet fully understood. This is especially the case when dealing with colloids that are soft, deformable, and permeable. In this paper, we propose a methodology for building a model that is able to predict the performance (flux, concentration profiles) of the filtration of such objects in relation with the operating conditions. This is done by focusing on the case of milk filtration, all experiments being performed with dispersions of milk casein micelles, which are sort of ″natural″ colloidal microgels. Using this example, we develop the general idea that a filtration model can always be built for a given colloidal dispersion as long as this dispersion has been characterized in terms of osmotic pressure Π and hydraulic permeability k. For soft and permeable colloids, the major issue is that the permeability k cannot be assessed in a trivial way like in the case for hard-sphere colloids. To get around this difficulty, we follow two distinct approaches to actually measure k: a direct approach, involving osmotic stress experiments, and a reverse-calculation approach, that consists of estimating k through well-controlled filtration experiments. The resulting filtration model is then validated against experimental measurements obtained from combined milk filtration/SAXS experiments. We also give precise examples of how the model can be used, as well as a brief discussion on the possible universality of the approach presented here.

Item Type:Article
Additional Information:Thanks to American Chemical Society editor. The definitive version is available at http://pubs.acs.org The original PDF of the article can be found at Langmuir website : http://dx.doi.org/10.1021/la402865p
HAL Id:hal-01209555
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:Other partners > Agrocampus Ouest (FRANCE)
French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE)
French research institutions > Institut National de la Recherche Agronomique - INRA (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE)
Laboratory name:
Institut National de la Recherche Agronomique (INRA) - Région Bretagne
Deposited On:14 Feb 2014 12:49

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