Renault, Cyril and Roche, Jérôme
and Ciumag, Mihaela Raluca
and Tzedakis, Théodore
and Colin, Stéphane and Groenen Serrano, Karine
and Reynes, Olivier
and André-Barrès, Christiane and Winterton, Peter
Design and optimization of electrochemical microreactors for continuous electrosynthesis.
(2012)
Journal of Applied Electrochemistry, 42 (9). 667-677. ISSN 0021-891X
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(Document in English)
PDF ( Author's version) - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader 438kB |
Official URL: http://dx.doi.org/10.1007/s10800-012-0445-x
Abstract
The study focuses on the design and construction, as well as the theoretical and experimental optimization of electrochemical filter press microreactors for the electrosynthesis of molecules with a high added value. The main characteristics of these devices are firstly a high-specific electrochemical area to increase conversion and selectivity, and secondly the shape and size of themicrochannels designed for a uniform residence time distribution of the fluid. A heat exchanger is integrated into the microstructured electrode to rapidly remove (or supply) the heat required in exo- or endothermic reactions. The microreactors designed are used to perform-specific electrosynthesis reactions such as thermodynamically unfavorable reactions (continuous NADH regeneration), or reactions with high enthalpy changes.
Item Type: | Article |
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Additional Information: | Thanks to Springer editor. The original PDF of the article can be found at Journal of Applied Electrochemistry website : http://www.springer.com/chemistry/electrochemistry/journal/10800 |
HAL Id: | hal-00878979 |
Audience (journal): | International peer-reviewed journal |
Uncontrolled Keywords: | |
Institution: | French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE) Université de Toulouse > Ecole nationale supérieure des Mines d'Albi-Carmaux - IMT Mines Albi (FRANCE) Université de Toulouse > Institut National Polytechnique de Toulouse - Toulouse INP (FRANCE) Université de Toulouse > Institut National des Sciences Appliquées de Toulouse - INSA (FRANCE) Université de Toulouse > Institut Supérieur de l'Aéronautique et de l'Espace - ISAE-SUPAERO (FRANCE) Université de Toulouse > Université Toulouse III - Paul Sabatier - UT3 (FRANCE) |
Laboratory name: | |
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Deposited On: | 31 Oct 2013 12:22 |
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