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Photochemical synthesis of a “cage” compound in a microreactor: Rigorous comparison with a batch photoreactor

Aillet, Tristan and Loubiere, Karine and Dechy-Cabaret, Odile and Prat, Laurent E. Photochemical synthesis of a “cage” compound in a microreactor: Rigorous comparison with a batch photoreactor. (2013) Chemical Engineering and Processing: Process Intensification, Vol. 64. pp. 38-47. ISSN 0255-2701

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Official URL: http://dx.doi.org/10.1016/j.cep.2012.10.017

Abstract

An intramolecular [2 + 2] photocycloaddition is performed in a microphotoreactor (0.81 mL) built by winding FEP tubing around a commercially available Pyrex immersion well in which a medium pressure mercury lamp is inserted. A rigorous comparison with a batch photoreactor (225 mL) is proposed by means of a simple model coupling the reaction kinetics with the mass, momentum and radiative transfer equations. This serves as a basis to explain why the chemical conversion and the irradiation time are respectively increased and reduced in the microphotoreactor relative to those in the batch photoreactor. Through this simple model reaction, some criteria for transposing photochemical synthesis from a batch photoreactor to a continuous microphotoreactor are defined.

Item Type:Article
Additional Information:Thanks to Elsevier editor. The definitive version is available at : http://dx.doi.org/10.1016/j.cep.2012.10.017
HAL Id:hal-00881067
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - INPT (FRANCE)
Laboratory name:
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Deposited By: Vincent GERBAUD
Deposited On:23 Oct 2013 11:26

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