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Preparation of phosphine-functionalized polystyrene stars by metal catalyzed controlled radical copolymerization and their application to hydroformylation catalysis

Cardozo Perez, Andrés Fernando and Manoury, Eric and Julcour-Lebigue, Carine and Blanco, Jean-François and Delmas, Henri and Gayet, Florence and Poli, Rinaldo Preparation of phosphine-functionalized polystyrene stars by metal catalyzed controlled radical copolymerization and their application to hydroformylation catalysis. (2013) Dalton Transactions, vol. 42 (n° 25). pp. 9148 -9156. ISSN 1477-9226

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Official URL: http://dx.doi.org/10.1039/c3dt33082f

Abstract

Well defined star copolymers have been prepared by copper-catalyzed atom transfer radical copolymerization of styrene and styryldiphenylphosphine starting from a modified Boltorn™ H30 multifunctional initiator. These polymers and an analogue obtained by debromination of the arm ends with nBu3SnH have been used in combination with [Rh(acac)(CO)2] for the homogeneous phase hydroformylation of 1-octene.

Item Type:Article
Additional Information:Thanks to the Royal Society of Chemistry. The definitive version is available at http://pubs.rsc.org/en/content/articlepdf/2013/dt/c3dt33082f
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - INPT (FRANCE)
Other partners > Institut universitaire de France - IUF (FRANCE)
Université de Toulouse > Université Paul Sabatier-Toulouse III - UPS (FRANCE)
Laboratory name:
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Deposited By: Andres fernando CARDOZO PEREZ
Deposited On:21 Oct 2013 14:39

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