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Hg(II) trace electrochemical detection on gold electrode: Evidence for chloride adsorption as the responsible for the broad baseline

Hezard, Teddy and Laffont, Laure and Gros, Pierre and Behra, Philippe and Evrard, David Hg(II) trace electrochemical detection on gold electrode: Evidence for chloride adsorption as the responsible for the broad baseline. (2013) Journal of Electroanalytical Chemistry, vol. 697. pp. 28-31. ISSN 1572-6657

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Official URL: http://dx.doi.org/10.1016/j.jelechem.2013.03.009

Abstract

Investigations were performed in order to clarify the origin of the broad baseline observed during Hg(II) trace electrochemical detection on gold electrode in the presence of Cl- anions. The influence of Cl- concentration on the shape of the voltammograms was studied in the presence and in the absence of Bovine Serum Albumin (BSA) in order to bring out adsorption/desorption processes. On the basis of these experiments, and contrary to what has been proposed by several authors in the literature, it was proved that the broad baseline does not result from calomel (Hg2Cl2) formation but is rather related to an interaction between Cl- and polycrystalline Au electrode surface. The evolution of the shape of the baseline was also studied in the presence of other halide anions, namely F-, Br-, and I-. The latter two were found to induce a broad baseline similar to that recorded in the presence of Cl-. Finally, it was shown that BSA addition is not suitable for Hg(II) detection since it prevents Hg(0) deposition onto the electrode surface.

Item Type:Article
Additional Information:Thanks to Elsevier editor. The definitive version is available at http://www.sciencedirect.com The original PDF of the article can be found at Journal of Electroanalytical Chemistry website : http://dx.doi.org/10.1016/j.jelechem.2013.03.009
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - INPT (FRANCE)
French research institutions > Institut National de la Recherche Agronomique - INRA (FRANCE)
Université de Toulouse > Université Paul Sabatier-Toulouse III - UPS (FRANCE)
Other partners > Fondation de Coopération Scientifique Science Technique Aéronautique et Espace - FCS STAE (FRANCE)
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Deposited By: David Evrard
Deposited On:17 Apr 2013 08:45

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