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Lithium conducting solid electrolyte Li1.3Al0.3Ti1.7(PO4)3 obtained via solution chemistry

Duluard, Sandrine Nathalie and Paillassa, Aude and Puech, Laurent and Vinatier, Philippe and Turq, Viviane and Rozier, Patrick and Lenormand, Pascal and Taberna, Pierre-Louis and Simon, Patrice and Ansart, Florence Lithium conducting solid electrolyte Li1.3Al0.3Ti1.7(PO4)3 obtained via solution chemistry. (2013) Journal of the European Ceramic Society, 33 (6). 1145-1153. ISSN 0955-2219

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Official URL: https://doi.org/10.1016/j.jeurceramsoc.2012.08.005

Abstract

NaSICON-type lithium conductor Li1.3Al0.3Ti1.7(PO4)3 (LATP) is synthesized with controlled grain size and composition using solution chemistry. After thermal treatment at 850 C, sub-micronic crystallized powders with high purity are obtained. They are converted into ceramic through Spark Plasma Sintering at 850–1000 C. By varying the processing parameters, pellet with conductivities up to 1.6 * 10−4 S/cm with density of 97% of the theoretical density have been obtained. XRD, FEG-SEM, ac-impedance and Vickers indentation were used to characterize the products. The influence of sintering parameters on pellet composition, microstructure and conductivity is discussed in addition to the analysis of the mechanical behavior of the grains interfaces.

Item Type:Article
Additional Information:Thanks to Elsevier editor. The definitive version is available at http://www.sciencedirect.com/science/article/pii/S0955221912004426
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - INPT (FRANCE)
Other partners > Université de Bordeaux 1 (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UPS (FRANCE)
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Deposited By: cirimat webmestre
Deposited On:21 Jun 2013 14:26

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