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Spin state dependence of electrical conductivity of spin crossover materials

Rotaru, Aurelian and Gural'skiy, Il'ya A. and Molnar, Gabor and Salmon, Lionel and Demont, Philippe and Bousseksou, Azzedine Spin state dependence of electrical conductivity of spin crossover materials. (2012) Chemical Communications, vol. 48 (n° 35). pp. 4163-4165. ISSN 1359-7345

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Official URL: http://dx.doi.org/10.1039/C2CC30528C

Abstract

We studied the spin state dependence of the electrical conductivity of the spin crossover compound [Fe(Htrz)2(trz)](BF4) (Htrz = 1H-1,2,4-triazole) by means of dc electrical measurements. The low spin state is characterized by higher conductance and lower thermal activation energy of the conductivity, when compared to the high spin state.

Item Type:Article
Additional Information:Thanks to Royal Society of Chemistry. The definitive version is available at http://pubs.rsc.org/en/content/articlelanding/2012/cc/c2cc30528c
HAL Id:hal-00842997
Audience (journal):International peer-reviewed journal
Uncontrolled Keywords:
Institution:French research institutions > Centre National de la Recherche Scientifique - CNRS (FRANCE)
Université de Toulouse > Institut National Polytechnique de Toulouse - INPT (FRANCE)
Other partners > Taras Shevchenko National University of Kyiv (UKRAIN)
Other partners > Université Pierre et Marie Curie, Paris 6 - UPMC (FRANCE)
Université de Toulouse > Université Toulouse III - Paul Sabatier - UPS (FRANCE)
Other partners > Universitatea Stefan cel Mare Suceava - USU (ROMANIA)
Other partners > Ecole Polytechnique (FRANCE)
Other partners > Université Paris-Sud 11 (FRANCE)
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Deposited By: cirimat webmestre
Deposited On:09 Jul 2013 15:06

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